I think it is designed this way as best practice. DSM doesn't have to worry about which volume the photo folder is on for services that need it, it just needs to know the static path to the symbolic link. The installer service will do the linking to the right volume.
I think changing the Symbolic link will be fine and preferred over modifying the Apache configuration for Photo Station. It would probably be broken on installing the package again though.
I have many DiskStations, I will run a test for you if I have some time.