Hi,
/proc/acpi/events method is for quite a long time marked as deprecated and newest Synology kernel used in DSM 5.2 is compiled without it (ACPI_PROC_EVENT). I have not found a way to compile this as a .ko module, so I am affraid the only way to make it work is to recompile whole kernel. Better way is not to use /proc/acpi/events and acpid, but to switch to newer input layer method implemented in acpid2. You can follow dilshodm's steps on page 9 of this thread and after loading evdev.ko module everything is working again.