well under 6.7 dunno if you can with 6.5 or below if you use NFS you can specify the ip's of the datastore/s
so i have a listed one with 10GBE in the esx and the dsm with 4 diffrent nics ip's and can get over 550MB a sec throughput
but this is with a Synology device,
Have tried making a virtual dsm in esx with a nvme drive backing and cannot get the same speed
but hey ho