Sorry for my bad english.
I also use APC UPS without USB, here is my modifying the way in the new version(5.2-5592 update 4) of the DSM.
1.Edit /usr/syno/etc/ups/ups.conf
[ups]
driver = apcsmart
port = /dev/ttyS0 <--Changed to your
cable = 940-0095B
2.Modify /usr/syno/etc/rc.sysv/ups-usb.sh
at 88 line
original
local DRV_LIST="usbhid-ups blazer_usb bcmxcp_usb richcomm_usb tripplite_usb"
after modify
local DRV_LIST="apcsmart usbhid-ups blazer_usb bcmxcp_usb richcomm_usb tripplite_usb"
3.Edit/etc/rc.local
at #!/bin/sh below add
/usr/syno/etc/rc.sysv/ups-usb.sh start
4.Download https://github.com/networkupstools/nut/raw/master/data/cmdvartab this files
and put it to /usr/syno/share/ folder
5.Restart your NAS,and enjoy it!